کاربرد ژئوپلیمرها درتصفیه فاضلاب

نوع مقاله : مقاله علمی-پژوهشی

نویسندگان

1 دانشجوی دکتری مهندسی سیستمهای انرژی، انرژی ومحیط زیست، گروه مهندسی محیط زیست، دانشگاه تهران، تهران، ایران

2 استاد، گروه مهندسی محیط زیست، دانشکده محیط زیست، دانشگاه تهران، تهران، ایران

3 دانشجوی دکتری مهندسی عمران – مهندسی و مدیریت ساخت، گروه مهندسی و مدیریت ساخت، دانشگاه آزاد اسلامی واحد علوم و تحقیقات، تهران، ایران

چکیده

توسعه سریع فناوری های پیشرفته در دنیا باعث افزایش تأثیرگذاری در تجمع هر روزه فلزات سنگین در زندگی روزمره از طریق فاضلاب می شود. تماس طولانی مدت بدن انسان با فلزات سنگین منجر به ابتلا به انواع عفونت ها و بیماری ها می شود. از دیدگاه محیط زیستی و اقتصادی، جذب، فرآیند قابل قبولی است که می تواند در تصفیه فاضلاب مورد استفاده قرار گیرد. با این حال، استفاده از جاذب های پذیرفته شده و پرهزینه کربن فعال باعث شده است تا بدنبال جایگزینی مناسب برای کربن فعال باشند. مطالعات بسیاری در مورد خواص فیزیکی وشیمیایی ژئوپلیمر صورت گرفته است که باعث جلب توجه ،جهت جایگزینی با کربن فعال در تصفیه فلزات سنگین شده است. در این مقاله تلاش شده است که براساس شواهد  علمی ،جذب فلزات سنگین با استفاده از ژئوپلیمر مورد بررسی قرار گیرد.

کلیدواژه‌ها


[1]- Fu, F., and Wang, Q., 2011, Removal of heavy metal ions from wastewaters: a review, Journal of environmental management, 92, 3, 407-418.‏
[2]- Metcalf and Eddy, Inc., 2003, Wastewater Engineering, Treatment and Reuse. 4th Edition, McGraw-Hill, New York.
[3]- Javadian, H., Ghorbani, F., Tayebi, H. A., and Asl, S. H., 2015, Study of the adsorption of Cd (II) from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies, Arabian Journal of Chemistry, 8, 6, 837-849.‏
[4]-Salam, O. E. A., Reiad, N. A., and ElShafei, M. M., 2011, A study of the removal characteristics of heavy metals from wastewater by low-cost adsorbents, Journal of Advanced Research, 2, 4, 297-303.‏
[5]- Wang, S., Li, L., and Zhu, Z. H., 2007, Solid-state conversion of fly ash to effective adsorbents for Cu removal from wastewater, Journal of hazardous materials, 139, 2, 254-259.‏
[6]- Lee, C. G., Song, M. K., Ryu, J. C., Park, C., Choi, J. W., & Lee, S. H., 2016, Application of carbon foam for heavy metal removal from industrial plating wastewater and toxicity evaluation of the adsorbent, Chemosphere, 153, 1-9.‏
[7]- Minju, J., Linoshka, S., Marleisa, A., Juliana, S. J., and Sangchul, H., 2015, Optimum mix design of fly ash geopolymer paste and its use in pervious concrete for removal of fecal coliforms and phosphorus in water, Construction and Building Materials, 93, 1097-1104
[8]- Mohammad, S., Al-Harahsheh, K., A., Leema, A., Muhammad, H., and Mehaysen, M., 2015, Fly ash based geopolymer for heavy metal removal: A case study on copper removal, Journal of Environmental Chemical Engineering, 3, 1669-1677.    
[9]- Gharzouni, A., Vidal, L., Essaidi, N., Joussein, E., and Rossignol, S., 2016, Recycling of geopolymer waste: Influence on geopolymer formation and mechanical properties, Materials & Design. 94. 10.1016/j.matdes.2016.01.043.
[10]-Ahmaruzzaman, M., 2011, Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals, Advances in Colloid and Interface Science, 166, 36-59.
[11]- Abas, S. N. A., Ismail, M. H. S., Kamal, M. L. and Izhar, S., 2013, Adsorption process of heavy metals by low-cost adsorbent: A review, World Application Science Journal, 28, 1518–1530.
[12]- Motsi, T., Rowson, N. A. and Simmons, M. J. H., 2009, Adsorption of Heavy Metals from Acid Mine Drainage by Natural Zeolite, International Journal of Mineral Processing, 92, 42-48.
[13]- Liu, H. H., Sang, S. H., 2010, Study on the law of heavy metal leaching in municpal solid waste landfill, Environment Monitoring Assessment, 165, 349–363.
[14]- Phair, J. W., Van Deventer, J. S. J., and Smith, J. D., 2004, Effect of Al source and alkali activation on Pb and Cu immobilisation in fly-ash based “geopolymers”. Applied Geochemistry, 19(3), 423-434.‏
[15]-  Waijarean, N., Asavapisit, S., and Sombatsompop, K., 2014, Strength and microstructure of water treatment residue-based geopolymers containing heavy metals, Construction and Building Materials, 50, 486-491.‏
[16]- Nikolić, V., Komljenović, M., Baščarević, Z., Marjanović, N., Miladinović, Z., and Petrović, R., 2015, The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers, Construction and Building materials, 94, 361-370.‏
[17]- Ge, Y., Yuan, Y., Wang, K., He, Y., and Cui, X., 2015, Preparation of geopolymer-based inorganic membrane for removing Ni2+ from wastewater, Journal of hazardous materials, 299, 711-718.‏
[18]- Al-Zboon, K., Al-Harahsheh, M. S., and Hani, F. B., 2011, Fly ash-based geopolymer for Pb removal from aqueous solution, Journal of Hazardous Materials, 188, (1-3), 414-421.‏
[19]- Luukkonen, T., Sarkkinen, M., Kemppainen, K., Rämö, J., and Lassi, U., 2016, Metakaolin geopolymer characterization and application for ammonium removal from model solutions and landfill leachate, Applied Clay Science, 119, 266-276.‏
[20]- Andrejkovičová, S., Sudagar, A., Rocha, J., Patinha, C., Hajjaji, W., da Silva, E. F.,and Rocha, F., 2016, The effect of natural zeolite on microstructure, mechanical and heavy metals adsorption properties of metakaolin based geopolymers, Applied Clay Science, 126, 141-152.‏
[21]- Williams, C. D., and Roberts, C. L., 2009, A comparative study of two methods for the synthesis of fly ash-based sodium and potassium type zeolites, Fuel, 88(8), 1403-1416.‏
[22]-Esparham, A., Moradikhou, A. B., & Jamshidi Avanaki, M., 2020, Effect of Various Alkaline Activator Solutions on Compressive Strength of Fly Ash-Based Geopolymer Concrete, Journal of civil Engineering and Materials Application, 4(2), 115-123.‏
[23]- Esparham, A., Moradikhou, A. B., Andalib, F. K., & Avanaki, M. J., 2021, Strength characteristics of granulated ground blast furnace slag-based geopolymer concrete, Advances in concrete construction, 11, 3, 219-229.‏
[24]- Esparham, A., and Moradikhou, A. B., 2021, A Novel Type of Alkaline Activator for Geopolymer Concrete Based on Class C Fly Ash, Advance Researches in Civil Engineering, 3, 1, 1-13.‏
[25]- Esparham, A., 2020, Factors Influencing Compressive Strength of Metakaolin-based Geopolymer Concrete, Modares Civil Engineering journal, 20, 1, 6-15.‏
[26]- Moradikhou, A. B., Esparham, A., and Avanaki, M. J., 2019, Effect of Hybrid Fibers on Water absorption and Mechanical Strengths of Geopolymer Concrete based on Blast Furnace Slag, Journal of civil Engineering and Materials Application, 3, 4, 195-211.‏
[27]- Esparham, A., and Moradikhou, A. B., 2021, Factors Influencing Compressive Strength of Fly Ash-based Geopolymer Concrete, Amirkabir Journal of Civil Engineering, 53, 3, 21-31.‏
[28]- Esparham, A., Hosseni, M. H., Mousavi Kashi, A., Emami, F., and Moradikhou, A. B., 2020, Impact of Replacing Kaolinite with Slag, Fly Ash and Zeolite on the Mechanical Strengths of Geopolymer Concrete Based on Kaolinite, Building Engineering & Housing Science, 13, 24, 9-15.‏
[29]- Moradikhou, A. B, Hosseini, M. H., Mousavi Kashi, A., Emami, F., and Esparham, A., 2020, Effect of Simple and Hybrid Polymer Fibers on Mechanical Strengths and High-temperature Resistance of Metakaolin-based Geopolymer Concrete, IQBQ, 20, 2, 147-161
[30]- Yao, Z. T., Ji, X. S., Sarker, P. K., Tang, J. H., Ge, L. Q., Xia, M. S., and Xi, Y. Q., 2015, A comprehensive review on the applications of coal fly ash, Earth-Science Reviews, 141, 105-121.‏
[31]- Li, L., Wang, S., and Zhu, Z., 2006, Geopolymeric adsorbents from fly ash for dye removal from aqueous solution, Journal of colloid and interface science, 300, 1, 52-59.‏
[32]- Albadarin, A. B., Mangwandi, C., Ala’a, H., Walker, G. M., Allen, S. J., and Ahmad, M. N., 2012, Kinetic and thermodynamics of chromium ions adsorption onto low-cost dolomite adsorbent, Chemical Engineering Journal, 179, 193-202.‏
[33]- Lim, A. P., and Aris, A. Z., 2014, A review on economically adsorbents on heavy metals removal in water and wastewater, Reviews in Environmental Science and Bio/Technology, 13, 2, 163-181.‏
[34]- Van Jaarsveld, J. G. S., Van Deventer, J. S., and Lukey, G. C., 2002, The effect of composition and temperature on the properties of fly ash-and kaolinite-based geopolymers, Chemical Engineering Journal, 89, 1-3, 63-73.